(Pyridino-15-crown-5-κ5N,O,O′,O′′,O′′′)bis(thiocyanato-κN)manganese(II)
نویسندگان
چکیده
منابع مشابه
(Pyridino-15-crown-5-κ5 N,O,O′,O′′,O′′′)bis(thiocyanato-κN)manganese(II)
The title complex, [Mn(NCS)(2)(C(13)H(19)NO(4))] {systematic name: [3,6,9,12-tetra-oxa-18-aza-bicyclo-[12.3.1]octa-cosa-14(18),15,17-triene-κ(5)N,O,O',O'',O''']bis-(thio-cyanato-κN)manganese(I-I)}, was obtained by the reaction of MnCl(2)·4H(2)O and NaSCN with pyridino-15-crown-5. The Mn(2+) center has a distorted penta-gonal bipyramidal coordination geometry, coordinated by four O atoms and one...
متن کامل4′-Formylbenzo-15-crown-5
IN THE TITLE COMPOUND (SYSTEMATIC NAME 17-formyl-2,5,8,11,14-penta-oxabicyclo-[13.4.0]nona-deca-15,17,19-triene), C(15)H(20)O(6), the 15-crown-5 ring adopts a twisted conformation. The formyl group is coplanar with the benzene ring. The crystal packing is stabilized by C-H⋯O inter-actions involving the C=O group and ether O atoms as acceptors and methyl-ene CH groups as donors.
متن کاملAquachloridodimethylphenyltin(IV)–15-crown-5 (2/1)
The Sn(IV) atom in the title compound, 2[Sn(CH(3))(2)(C(6)H(5))Cl(H(2)O)]·C(10)H(20)O(5), exists in a trans-C(3)SnClO trigonal bipyramidal geometry in which the organo substituents occupy the equatorial sites. The coordinated water mol-ecule forms two hydrogen bonds to the 15-crown-5 mol-ecule, which is disordered about a center of inversion.
متن کاملMore examples of the 15-crown-5...H2O-M-OH2...15-crown-5 motif, M = Al3+, Cr3+ and Pd2+.
Five structures of co-crystals grown from aqueous solutions equimolar in 15-crown-5 (or 15C5) and [M(H(2)O)(6)](NO(3))(n), M = Al(3+), Cr(3+) and Pd(2+), are reported. The hydrogen-bonding patterns in all are similar: metal complexes including the fragment trans-H(2)O-M-OH(2) alternate with 15C5 molecules, to which they are hydrogen bonded, to form stacks. A literature survey shows that this hy...
متن کاملBis(benzo-15-crown-5-κ5 O)strontium bis(triiodide)
The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro-methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (-) anions which are arranged in alternating layers parallel to (010). The triiodide anions are located in general positions, whereas the ca...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s160053680800679x